Publications

2024

K. Wurst, M. Birkle, K. J. Scherer, S. Mecking*:
Circular Melt-Spun Textile Fibers from Polyethylene-like Long-Chain Polyesters.
ACS Appl. Polym. Mater. 2024, ASAP. DOI: 10.1021/acsapm.4c01570

M. Baur, R. Habé, S. Mecking*:
Aqueous Keto-Polyethylene Dispersions from Catalytic Copolymerization of Ethylene and Carbon Monoxide in Water.
ACS Macro Lett. 2024, 13, 841 - 846. DOI: 10.1021/acsmacrolett.4c00313

S. T. Schwab, T. F. Nelson, S. Mecking*:
Chemically Recyclable and Biodegradable Vulcanized Rubber.
ACS Sustainable Chem. Eng. 2024, 12, 6281 - 6288. DOI: 10.1021/acssuschemeng.3c08435

M. Eck, S. Mecking*:
Closed-Loop Recyclable and Nonpersistent Polyethylene-like Polyesters.
Acc. Chem. Res. 2024, 57, 971 - 980. DOI: 10.1021/acs.accounts.3c00811

S. T. Schwab, M. Baur, T. F. Nelson, S. Mecking*:
Synthesis and Deconstruction of Polyethylene-type Materials.
Chem. Rev. 2024, 124, 2327 - 2351. DOI: 10.1021/acs.chemrev.3c00587

M. Birkle, H. S. Mehringer, T. F. Nelson, S. Mecking*:
Aliphatic Polyester Materials from Renewable 2,3-Butanediol.
ACS Sustainable Chem. Eng. 2024, 12, 4156 - 4163. DOI: 10.1021/acssuschemeng.3c07665

H. Janani, S. F. Marxsen, M. Eck, S. Mecking, K. Tashiro, R. G. Alamo*:
Polymorphism and Stretch-Induced Transformations of Sustainable Polyethylene-Like Materials.
ACS Macro Lett. 2024, 13, 201 - 206. DOI: 10.1021/acsmacrolett.3c00639

F. De Stefano, M. Baur, C. De Rosa, S. Mecking*:
Keto-Polyethylenes with Controlled Crystallinity and Materials Properties from Catalytic Ethylene–CO–Norbornene Terpolymerization.
Macromolecules 2024, 57, 1072 - 1079. DOI: 10.1021/acs.macromol.3c02309

2023

F. Lin, M. Voccia, L. Odenwald, I. Göttker-Schnetmann, L. Falivene, L. Caporaso*, S. Mecking*:
Origin of Suppressed Chain Transfer in Phosphinephenolato Ni(II)-Catalyzed Ethylene Polymerization.
J. Am. Chem. Soc. 2023, 145, 27950 - 27957. DOI: 10.1021/jacs.3c06597

C. Hahn, I. Göttker-Schnetmann, I. Tzourtzouklis, M. Wagner, A. H. E. Müller, G. Floudas*, S. Mecking*, H. Frey*:
Nopadiene: A Pinene-Derived Cyclic Diene as a Styrene Substitute for Fully Biobased Thermoplastic Elastomers.
J. Am. Chem. Soc. 2023, 145, 26688 - 26698. DOI: 10.1021/jacs.3c08130

M. Eck, C. Stoltze, S. Mecking*:
Waxes from Long-Chain Aliphatic Difunctional Monomers.
ACS Sustainable Chem. Eng. 2023, 11, 16716 - 16721. DOI: 10.1021/acssuschemeng.3c06951

F. Conradt, V. Bezold, V. Wiechert, S. Huber, S. Mecking, A. Leitenstorfer*, R. Tenne*:
Electric-Field Fluctuations as the Cause of Spectral Instabilities in Colloidal Quantum Dots.
Nano Lett. 2023, 23, 9753 - 9759. DOI: 10.1021/acs.nanolett.3c02318

M. Baur, N. K. Mast, J. P. Brahm, R. Habé, T. O. Morgen, S. Mecking*.
High Density Polyethylene with In-Chain Photolyzable and Hydrolyzable Groups Enabling Recycling and Degradation.
Angew. Chem. Int. Ed. 2023, e202310990. DOI: 10.1002/anie.202310990

T. F. Nelson*, D. Rothauer, M. Sander, S. Mecking*:
Degradable and Recyclable Polyesters from Multiple Chain Length Bio- and Waste-Sourceable Monomers.
Angew. Chem. Int. Ed. 2023, e202310729. DOI: 10.1002/anie.202310729

A. Saumer, S. Mecking*:
Recyclable and Degradable Ionic-Substituted Long-Chain Polyesters.
ACS Sustainable Chem. Eng. 2023, 11, 12414 - 12422. DOI: 10.1021/acssuschemeng.3c03141

S. F. Marxsen, M. Häußler, M. Eck, S. Mecking, R. G. Alamo*:
Effect of CH2 Run Length on the Crystallization Kinetics of Sustainable Long-Spaced Aliphatic Polyesters.
Polymer 2023, 282, 126181. DOI: 10.1016/j.polymer.2023.126181

S. de Roo, F. Einsiedler, S. Mecking*:
Catalytic Biorefining of Natural Oils to Basic Olefinic Building Blocks of Proven Chemical Valorization Schemes.
Angew. Chem. Int. Ed. 2023, e202219222. DOI: 10.1002/anie.202219222

M. Eck, L. Bernabeu, S. Mecking*:
Polyethylene-Like Blends Amenable to Abiotic Hydrolytic Degradation.
ACS Sustainable Chem. Eng. 2023, 11, 4523 - 4530. DOI: 10.1021/acssuschemeng.2c07537

M. Eck, S. T. Schwab, T. F. Nelson, K. Wurst, S. Iberl, D. Schleheck, C. Link, G. Battagliarin, S. Mecking*:
Biodegradable High Density Polyethylene-Like Material.
Angew. Chem. Int. Ed. 2023, 62, e202213438. DOI: 10.1002/anie.202213438

2022

M. Baur, S. Mecking*:
Polyethylenes with Combined In-Chain and Side-Chain Functional Groups from Catalytic Terpolymerization of Carbon Monoxide and Acrylate.
ACS Macro Lett. 2022, 11, 1207 - 1211. DOI: 10.1021/acsmacrolett.2c00459

N. S. Schunck*, S. Mecking*:
In Vivo Olefin Metathesis in Microalgae Upgrades Lipids to Building Blocks for Polymers and Chemicals.
Angew. Chem. Int. Ed. 2022, e202211285. DOI: 10.1002/anie.202211285

A. Fuchs, S. Mecking*:
Controlled Cobalt-Mediated Free-Radical Co- and Terpolymerization of Carbon Monoxide.
J. Am. Chem. Soc. 2022, 144, 15879 - 15884. DOI: 10.1021/jacs.2c07200

M. Voccia, L. Odenwald, M. Baur, F. Lin, L. Falivene, S. Mecking*, L. Caporaso*:
Mechanistic Insights into Ni(II)-Catalyzed Nonalternating Ethylene–Carbon Monoxide Copolymerization.
J. Am. Chem. Soc. 2022, 144, 15111 - 15117. DOI: 10.1021/jacs.2c04563

J. Park, A. Staiger, S. Mecking, K. I. Winey*:
Enhanced Li-Ion Transport through Selectively Solvated Ionic Layers of Single-Ion Conducting Multiblock Copolymers.
ACS Macro Lett. 2022, 11, 1008 - 1013. DOI: 10.1021/acsmacrolett.2c00288

L. Odenwald, F. P. Wimmer, N. K. Mast, M. G. Schußmann, M. Wilhelm, S. Mecking*:
Molecularly Defined Polyolefin Vitrimers from Catalytic Insertion Polymerization.
J. Am. Chem. Soc. 2022, 144, 13226 - 13233. DOI: 10.1021/jacs.2c03778

F. Lin, S. Mecking*:
Hydrophilic Catalysts with High Activity and Stability in Aqueous Polymerization to High Molecular Weight Polyethylene.
Angew. Chem. Int. Ed. 2022, e202203923. DOI: 10.1002/anie.202203923

B. A. Paren, M. Häußler, P. Rathenow, S. Mecking*, K. I. Winey*:
Decoupled Cation Transport within Layered Assemblies in Sulfonated and Crystalline Telechelic Polyethylenes.
Macromolecules 2022, 55, 2813 - 2820. DOI: 10.1021/acs.macromol.2c00132

J. Park, A. Staiger, S. Mecking*, K. I. Winey*:
Ordered Nanostructures in Thin Films of Precise Ion-Containing Multiblock Copolymers.
ACS Cent. Sci. 2022, 8, 388 - 393. DOI: 10.1021/acscentsci.1c01594

2021

F. Lin, T. O. Morgen, S. Mecking*:
Living Aqueous Microemulsion Polymerization of Ethylene with Robust Ni(II) Phosphinophenolato Catalysts.
J. Am. Chem. Soc. 2021, 143, 20605 - 20608. DOI: 10.1021/jacs.1c10488

M. Baur, F. Lin, T. O. Morgen, L. Odenwald, S. Mecking*:
Polyethylene Materials with In-Chain Ketones from Non-Alternating Catalytic Copolymerization.
Science 2021, 374, 604 - 607. DOI: 10.1126/science.abi8183
Science 2021, 374, 604 - 607. DOI: 10.1126/science.abi8183 (alternative link)

J. Park, A. Staiger, S. Mecking, K. I. Winey*:
Sub-3-Nanometer Domain Spacings of Ultrahigh-χ Multiblock Copolymers with Pendant Ionic Groups.
ACS Nano 2021, 15, 16738 - 16747. DOI: 10.1021/acsnano.1c06734

A. Staiger, B. A. Paren, R. Zunker, S. Hoang, M. Häußler, K. I. Winey*, S. Mecking*:
Anhydrous Proton Transport within Phosphonic Acid Layers in Monodisperse Telechelic Polyethylenes.
J. Am. Chem. Soc. 2021, 143, 16725 - 16733. DOI: 10.1021/jacs.1c08031

S. F. Marxsen, M. Häußler, S. Mecking, R. G. Alamo*:
Unlayered–Layered Crystal Transition in Recyclable Long-Spaced Aliphatic Polyesters.
ACS Appl. Polym. Mater. 2021, 3, 5243 - 5256. DOI: 10.1021/acsapm.1c01025

S. F. Marxsen, M. Häußler, S. Mecking, R. G. Alamo*:
Crystallization of Long-Spaced Precision Polyacetals III: Polymorphism and Crystallization Kinetics of Even Polyacetals Spaced by 6 to 26 Methylenes.
Polymers 2021, 13, 1560. DOI: 10.3390/polym13101560

B. Zhao, B. Gothe, A. Groh, T. Schmaltz, J. Will, H.-G. Steinrück, T. Unruh, S. Mecking, M. Halik*:
Oligothiophene Phosphonic Acids for Self-Assembled Monolayer Field-Effect Transistors.
ACS Appl. Mater. Interfaces 2021, 13, 32461 - 32466. DOI: 10.1021/acsami.1c05764

A. Sickinger, S. Mecking*:
Origin of the Anisotropy and Structure of Ellipsoidal Poly(fluorene) Nanoparticles.
Macromolecules 2021, 54, 5267 - 5277. DOI: 10.1021/acs.macromol.1c00597

E. Schiebel, M. Voccia, L. Falivene, I. Göttker-Schnetmann, L. Caporaso*, S. Mecking*:
Neutral Unsymmetrical Coordinated Cyclophane Polymerization Catalysts.
Angew. Chem. Int. Ed. 2021, 60, 18472 - 18477. DOI: 10.1002/anie.202105401

F. P. Wimmer, V. Ebel, F. Schmidt, S. Mecking*:
Compartmentalized Polymerization in Aqueous and Organic Media to Low-entangled Ultra High Molecular Weight Polyethylene.
Polym. Chem. 2021, 12, 3116 - 3123. DOI: 10.1039/D1PY00394A

A. Flachmüller, S. Mecking, C. Peter*:
Coarse Grained Simulation of the Aggregation and Structure Control of Polyethylene Nanocrystals.
J. Phys.: Condensed Matter 2021, 33, 264001. DOI: 10.1088/1361-648X/abf881

J. Park, A. Staiger, S. Mecking,* K. Winey*:
Structure-Property Relationships in Single-ion Conducting Multiblock Copolymers: A Phase Diagram and Ionic Conductivities.
Macromolecules 2021, 54, 4269 - 4279. DOI: 10.1021/acs.macromol.1c00493

E. Schiebel, M. Voccia, L. Falivene, L. Caporaso*, S. Mecking*:
The Impact of Charge in a Ni(II) Polymerization Catalyst.
ACS Catal. 2021, 11, 5358 - 5368. DOI: 10.1021/acscatal.1c00778

M. Häußler, M. Eck, D. Rothauer, S. Mecking*:
Closed-Loop Recycling of Polyethylene-Like Materials.
Nature 2021, 590, 423 - 427. DOI: 10.1038/s41586-020-03149-9

P. Gumbsheimer, F. Conradt, Y. Behovits, S. Huber, C. Hinz, C. Negele, S. Mecking, D. Seletskiy, A. Leitenstorfer*:
Enhanced Determination of Emission Fine Structure and Orientation of Individual Quantum Dots Based on Correction Algorithm for Spectral Diffusion.
J. Phys. D: Appl. Phys. 2021, 54, 155106. DOI: 10.1088/1361-6463/abda83

C. Wang, X. Kang, S. Dai, F. Cui, Y. Li, H. Mu, S. Mecking*, Z. Jian*:
Efficient Suppression of Chain Transfer and Branching via C_s‐Type Shielding in a Neutral Nickel(II) Catalyst.
Angew. Chem. Int. Ed. 2021, 60, 4018 - 4022. DOI: 10.1002/anie.202013069

2020

S. Mecking*, M. Schnitte:
Neutral Nickel(II) Catalysts: From Hyperbranched Oligomers to Nanocrystal-Based Materials.
Acc. Chem. Res. 2020, 53, 2738 - 2752. DOI: 10.1021/acs.accounts.0c00540

I. Göttker-Schnetmann*, S. Mecking:
A Practical Synthesis of [(tmeda)Ni(CH₃)₂], Isotopically Labeled [(tmeda)Ni(¹³CH₃)₂], and Neutral Chelated-Nickel Methyl Complexes.
Organometallics 2020, 39, 3433 - 3440. DOI: 10.1021/acs.organomet.0c00500

X. Zhang, S. F. Marxsen, P. Ortmann, S. Mecking, R. G. Alamo*:
Crystallization of Long-Spaced Precision Polyacetals II: Effect of Polymorphism on Isothermal Crystallization Kinetics.
Macromolecules 2020, 53, 7899 - 7913. DOI: 10.1021/acs.macromol.0c01443

T. O. Morgen, M. Baur, I. Göttker-Schnetmann, S. Mecking*:
Photodegradable Branched Polyethylenes from Carbon Monoxide Copolymerization under Benign Conditions.
Nature Commun. 2020, 11, 3693. DOI: 10.1038/s41467-020-17542-5

S. Mecking*:
Polyethylene-like Materials from Plant Oils.
Phil. Trans. Royal Soc. A 2020, 378, 20190266. DOI: 10.1098/rsta.2019.0266

Y. Zhang, C. Wang, S. Mecking*, Z. Jian*:
Ultrahighly Branching of Main‐Chain‐Functionalized Polyethylenes by Inverted Insertion Selectivity.
Angew. Chem. Int. Ed. 2020, 59, 14296 - 14302. DOI: 10.1002/anie.202004763

S. M. Stadler, I. Göttker-Schnetmann, A. S. Fuchs, S. R. R. Fischer, S. Mecking*:
Catalytic Chain Transfer Polymerization to Functional Reactive End Groups for Controlled Free Radical Growth.
Macromolecules 2020, 53, 2362 - 2368. DOI: 10.1021/acs.macromol.0c00241

Direct Observation of Chain Lengths and Conformations in Oligofluorene Distributions from Controlled Polymerization by Double Electron–Electron Resonance. — Electron paramagnetic resonance methods unravel different chain lengths present and their relative share and individual conformations directly from measurements of endgroup distances on a mixture as obtained from a controlled polymerization.

D. Bücker, A. Sickinger, J. D. Ruiz Perez, M. Oestringer, S. Mecking*, M. Drescher*:
Direct Observation of Chain Lengths and Conformations in Oligofluorene Distributions from Controlled Polymerization by Double Electron–Electron Resonance.
J. Am. Chem. Soc. 2020, 142, 1952 - 1956. DOI: 10.1021/jacs.9b11404

Remote Perfluoroalkyl Substituents are Key to Living Aqueous Ethylene Polymerization. — Remote pentafluorophenyl groups suppress chain transfer and branch formation in Ni(II)-catalyzed ethylene polymerization.
This results in formation of high molecular weight linear polyethylene, which in aqueous polymerizations is obtained in the form of nanocrystals.

M. Schnitte, S. Lipinski, E. Schiebel, S. Mecking*:
Pentafluorophenyl Groups as Remote Substituents in Ni(II) Polymerization Catalysis.
Organometallics 2020, 39, 13 - 17.
DOI: 10.1021/acs.organomet.9b00784

Gyroid and Other Ordered Morphologies in Single-Ion Conducting Polymers and Their Impact on Ion Conductivity. — The incorporation of metal cations in polyethylene-based ionomers produces versatile morphologies, including the bicontinuous cubic gyroid phase. The gyroid morphology is capable of providing three-dimensional interconnected ion conducting pathways for improved ion transport.

L. Yan, C. Rank, S. Mecking*, K. I. Winey*:
Gyroid and Other Ordered Morphologies in Single-Ion Conducting Polymers and Their Impact on Ion Conductivity.
J. Am. Chem. Soc. 2020, 142, 857 - 866. DOI: 10.1021/jacs.9b09701

M. Schnitte, J. S. Scholliers, K. Riedmiller, S. Mecking*:
Remote Perfluoroalkyl Substituents are Key to Living Aqueous Ethylene Polymerization.
Angew. Chem. Int. Ed. 2020, 59, 3258 - 3263. DOI: 10.1002/anie.201913117
Angew. Chem. 2020, 132, 3284 - 3289. DOI: 10.1002/ange.201913117

2019

P. Kenyon, L. Falivene, L. Caporaso*, S. Mecking*:
Ancillary Ligands Impact Branching Microstructure in Late Transition Metal Polymerization Catalysis.
ACS Catal. 2019, 9, 11552 - 11556. DOI: 10.1021/acscatal.9b04028

C. Rank, L. Yan, S. Mecking*, K. I. Winey*:
Periodic Polyethylene Sulfonates from Polyesterification: Bulk and Nanoparticle Morphologies and Ionic Conductivities.
Macromolecules 2019, 52, 8466 - 8475. DOI: 10.1021/acs.macromol.9b01762

D. Bücker, A. Sickinger, J. D. Ruiz-Perez, M. Oestringer, S. Mecking*, M. Drescher*:
Direct Observation of Chain Lengths and Conformations in Oligofluorene Distributions from Controlled Polymerization by Double Electron-Electron Resonance.
ChemRxiv 2019. DOI: 10.26434/chemrxiv.10002785.v1

I. Göttker-Schnetmann, P. Kenyon, S. Mecking*:
Coordinative Chain Transfer Polymerization of Butadiene with Functionalized Aluminum Reagents.
Angew. Chem. Int. Ed. 2019, 58, 17777 - 17781. DOI: 10.1002/anie.201909843
Angew. Chem. 2019, 131, 17941 – 17945. DOI: 10.1002/ange.201909843

C. Rank, M. Häußler, P. Rathenow, M. King, C. Globisch, C. Peter*, S. Mecking*:
Anisotropic Extended-Chain Polymer Nanocrystals.
Macromolecules 2019, 52, 6142 - 6148. DOI: 10.1021/acs.macromol.9b00986

S. Huber, S. Mecking*:
Straightforward Synthesis of Conjugated Block Copolymers by Controlled Suzuki–Miyaura Cross-Coupling Polymerization Combined with ATRP.
Macromolecules 2019, 52, 5917 - 5924. DOI: 10.1021/acs.macromol.9b01165

D. Langford, I. Göttker-Schnetmann, F. P. Wimmer, L. A. Casper, P. Kenyon, R. F. Winter, S. Mecking*:
Tetrakis[3,5-bis(pentafluorosulfanyl)phenyl]borate: A Weakly Coordinating Anion Probed in Polymerization Catalysis.
Organometallics 2019, 38, 2710 - 2713. DOI: 10.1021/acs.organomet.9b00332

L. Yan, M. Häußler, J. Bauer, S. Mecking*, K. I. Winey*:
Monodisperse and Telechelic Polyethylenes Form Extended Chain Crystals with Ionic Layers.
Macromolecules 2019, 52, 4949 - 4956. DOI: 10.1021/acs.macromol.9b00962

X. Zhang, X. Zuo, P. Ortmann, S. Mecking, R. G. Alamo*:
Crystallization of Long-Spaced Precision Polyacetals I: Melting and Recrystallization of Rapidly Formed Crystallites.
Macromolecules 2019, 52, 4934 - 4948. DOI: 10.1021/acs.macromol.9b00922

M. Schnitte, A. Staiger, L. A. Casper, S. Mecking*:
Uniform Shape Monodisperse Single Chain Nanocrystals by Living Aqueous Catalytic Polymerization.
Nat. Commun. 2019, 10, 2592. DOI: 10.1038/s41467-019-10692-1

T. O. Morgen, H. Luttikhedde, S. Mecking*:
Aqueous Dispersions of Ethylene Copolymers and Their Laponite Clay Nanocomposites from Free-Radical Dispersion Polymerization.
Macromolecules 2019, 52, 4270 - 4277. DOI: 10.1021/acs.macromol.9b00305

J. Zimmerer, D. Pingen, S. K. Hess, T. Koengeter, S. Mecking*:
Integrated Extraction and Catalytic Upgrading of Microalgae Lipids in Supercritical Carbon Dioxide.
Green Chem. 2019, 21, 2428 - 2435. DOI: 10.1039/C9GC00312F

E. Schiebel, S. Santacroce, L. Falivene, I. Göttker-Schnetmann, L. Caporaso*, S. Mecking*:
Tailored Strength Neighboring Group Interactions Switch Polymerization to Dimerization Catalysis.
ACS Catal. 2019, 9, 3888 - 3894. DOI: 10.1021/acscatal.9b00129

Y. Liu, S. Mecking*:
A Synthetic Polyester from Plant Oil Feedstock by Functionalizing Polymerization.
Angew. Chem. Int. Ed. 2019, 58, 3346 - 3350. DOI: 10.1002/anie.201810914
Angew. Chem. 2019,131, 3384 - 3388. DOI: 10.1002/ange.201810914

S. Stadler, I. Göttker-Schnetmann, S. Mecking*:
Incorporation of Radicals during Ni(II)-Catalyzed Ethylene Insertion Polymerization.
ACS Catal. 2019, 9, 2760 - 2767. DOI: 10.1021/acscatal.8b04707

P. Ehrenreich, A. Groh, H. Goodwin, J. Huster, F. Deschler, S. Mecking*, L. Schmidt-Mende*:
Tailored Interface Energetics for Efficient Charge Separation in Metal Oxide-Polymer Solar Cells.
Sci. Rep. 2019, 9, 74. DOI: 10.1038/s41598-018-36271-w

Q. Tong, M. S. Schmidt, V. Wittmann*, S. Mecking*:
Multivalent Carbohydrate-Functionalized Polymer Nanocrystals.
Biomacromolecules 2019, 20, 294 - 304. DOI: 10.1021/acs.biomac.8b01460

2018

S. Majumder, H. Busch, P. Poudel, S. Mecking, G. Reiter*:
Growth Kinetics of Stacks of Lamellar Polymer Crystals.
Macromolecules 2018, 51, 8738 - 8745. DOI: 10.1021/acs.macromol.8b01765

Y. Liu, K. Dong, M. Beller, S. Mecking*:
Selective Long-Range Isomerization Carbonylation of a Complex Hyperbranched Polymer Substrate.
ACS Catal. 2018, 8, 9232 - 9237. DOI: 10.1021/acscatal.8b03117

D. Pingen, N. Klinkenberg, S. Mecking*:
Single-Step Catalytic Upgrading of Microalgae Biomass.
ACS Sustainable Chem. Eng. 2018, 6, 11219 - 11221.
DOI: 10.1021/acssuschemeng.8b02939

F. P. Wimmer, L. Caporaso, L. Cavallo, S. Mecking, L. Falivene*:
Mechanism of Insertion Polymerization of Allyl Ethers.
Macromolecules 2018, 51, 4525 - 4531. DOI: 10.1021/acs.macromol.8b00783

T. O. Morgen, M. Krumova, H. Luttikhedde, S. Mecking*:
Free-Radical Dispersion Polymerization of Ethylene with Laponite to Polyethylene-Clay Nanocomposite Particles.
Macromolecules 2018, 51, 4118 - 4128. DOI: 10.1021/acs.macromol.8b00440

P. Kenyon, M. Wörner, S. Mecking*:
Controlled Polymerization in Polar Solvents to Ultrahigh Molecular Weight Polyethylene.
J. Am. Chem. Soc. 2018, 140, 6685 - 6689. DOI: 10.1021/jacs.8b03223

V. Goldbach, M. Krumova, S. Mecking*:
Full-Range Interconversion of Nanocrystals and Bulk Metal with a Highly Selective Molecular Catalyst.
ACS Catal. 2018, 8, 5515 - 5525. DOI: 10.1021/acscatal.8b00981

D. Pingen, J. B. Schwaderer, J. Walter, J. Wen, G. Murray, D. Vogt, S. Mecking*:
Diamines for Polymer Materials via Direct Amination of Lipid‐ and Lignocellulose‐based Alcohols with NH3.
ChemCatChem 2018, 10, 3027 - 3033. DOI: 10.1002/cctc.201800365

D. Pingen, J. Zimmerer, N. Klinkenberg, S. Mecking*:
Microalgae Lipids as a Feedstock for the Production of Benzene.
Green Chem. 2018, 20, 1874 - 1878. Interview DOI: 10.1039/C8GC00423D

M. Baier, D. Wöll, S. Mecking*:
Diffusion of Molecular and Macromolecular Polyolefin Probes in Cylindrical Block Copolymer Structures As Observed by High Temperature Single Molecule Fluorescence Microscopy.
Macromolecules 2018, 51, 1873 - 1884. DOI: 10.1021/acs.macromol.8b00071

L. Falivene, T. Wiedemann, I. Göttker-Schnetmann, L. Caporaso, L. Cavallo*, S. Mecking*:
Control of Chain Walking by Weak Neighbouring Group Interactions in Unsymmetric Catalysts.
J. Am. Chem. Soc. 2018, 140, 1305 - 1312. DOI: 10.1021/jacs.7b08975

H. Leicht , J. Bauer, I. Göttker-Schnetmann, S. Mecking*:
Heterotelechelic and In-Chain Polar Functionalized Stereoregular Poly(dienes).
Macromolecules 2018, 51, 763 - 770. DOI: 10.1021/acs.macromol.7b02006

B. Schemmer, C. Kronenbitter, S. Mecking*:
Thermoplastic Polyurethane Elastomers with Aliphatic Hard Segments Based on Plant-oil Derived Long-Chain Diisocyanates.
Macromol. Mater. Eng. 2018, 303, 1700416. DOI: 10.1002/mame.201700416

S. K. Hess, B. Lepetit, P. G. Kroth, S. Mecking*:
Production of Chemicals from Microalgae Lipids - Status and Perspectives.
Eur. J. Lipid Sci. Technol. 2018, 120, 1700152. DOI: 10.1002/ejlt.201700152

N. Schuster, M. Krumova, F. Richter, A. Schneller, S. Mecking*:
High-Impact Polyamide Composites with Linear Ethylene–Norbornene Anhydride Copolymers from Insertion Polymerization.
Macromol. Mater. Eng. 2018, 303, 1700276. DOI: 10.1002/mame.201700276

2017

M. Baier, S. Mecking*:
Post- and Non-Metallocenes for Olefin Insertion Polymerization in Applied Homogeneous Catalysis with Organometallic Compounds.
(Eds.: M. Beller, B. Cornils, W. A. Herrmann, R. Paciello).
Wiley-VCH 2017, 1, 225 - 247. DOI: 10.1002/9783527651733.ch4

B. Gothe, T. de Roo, J. Will, T. Unruh, S. Mecking, M. Halik*:
Self-Assembled Monolayer Field-Effect Transistors based on Oligo-9,9’-dioctylfluorene Phosphonic Acids.
Nanoscale 2017, 9, 18584 - 18589. DOI: 10.1039/C7NR06090D

H. Leicht, I. Göttker-Schnetmann, S. Mecking*:
Stereoselective Copolymerization of Butadiene and Functionalized 1,3-Dienes with Neodymium-Based Catalysts.
Macromolecules 2017, 50, 8464 - 8468. DOI: 10.1021/acs.macromol.7b02007

P. Kenyon, S. Mecking*:
Pentafluorosulfanyl Substituents in Polymerization Catalysis.
J. Am. Chem. Soc. 2017, 139, 13786 - 13790. DOI: 10.1021/jacs.7b06745

H. Busch, E. Schiebel, A. Sickinger, S. Mecking*:
Ultralong-Chain-Spaced Crystalline Poly(H-phosphonate)s and Poly(phenylphosphonate)s.
Macromolecules 2017, 50, 7901 - 7910. DOI: 10.1021/acs.macromol.7b01368

J. Zimmerer, L. Williams, D. Pingen, S. Mecking*:
Mid-Chain Carboxylic Acids by Catalytic Refining of Microalgae Oil.
Green Chem. 2017, 19, 4865 - 4870. DOI: 10.1039/C7GC01484H

S. K. Hess, N. S. Schunck, V. Goldbach, D. Ewe, P. G. Kroth, S Mecking*:
Valorization of Unconventional Lipids from Microalgae or Tall Oil via a Selective Dual Catalysis One-Pot Approach.
J. Am. Chem. Soc. 2017, 139, 13487 - 13491. DOI: 10.1021/jacs.7b06957

M. L. Unbehauen, E. Fleige, F. Paulus, B. Schemmer, S. Mecking, S. D. Moré, R. Haag*:
Biodegradable Core-Multishell Nanocarriers: Influence of Inner Shell Structure on the Encapsulation Behavior of Dexamethasone and Tacrolimus.
Polymers 2017, 9, 316. DOI: 10.3390/polym9080316

D. Myers, T. Witt, A. Cyriac, M. Bown, S. Mecking*, C. K. Williams*:
Ring Opening Polymerization of Macrolactones: High Conversions and Activities Using an Yttrium Catalyst.
Polym. Chem. 2017, 8, 5780 - 5785. DOI: 10.1039/C7PY00985B

H. Leicht, I. Göttker-Schnetmann, S. Mecking*:
Synergetic Effect of Monomer Functional Group Coordination in Catalytic Insertion Polymerization.
J. Am. Chem. Soc. 2017, 139, 6823 - 6826. DOI: 10.1021/jacs.7b03087

T. Witt, M. Häußler, S. Kulpa, S. Mecking*:
Chain Multiplication of Fatty Acids to Precise Telechelic Polyethylene.
Angew. Chem. Int. Ed. 2017, 56, 7589 - 7594. DOI: 10.1002/anie.201702796
Angew. Chem. 2017, 129, 7697 - 7702. DOI: 10.1002/ange.201702796

J. D. R. Perez, S. Mecking*:
Anisotropic Polymer Nanoparticles with Tunable Emission Wavelengths by Intersegmental Chain Packing.
Angew. Chem. Int. Ed. 2017, 56, 6147 - 6151. DOI: 10.1002/anie.201701000
Angew. Chem. 2017, 129, 6243 - 6247. DOI: 10.1002/ange.201701000

H. Busch, S. Majumder, G. Reiter, S. Mecking*:
Semicrystalline Long-Chain Polyphosphoesters from Polyesterification.
Macromolecules 2017, 50, 2706 - 2713. DOI: 10.1021/acs.macromol.7b00243

C. Hintze, P. Korf, F. Degen, F. Schütze, S. Mecking, U. E. Steiner*, M. Drescher*:
Delocalization of Coherent Triplet Excitons in Linear Rigid Rod Conjugated Oligomers.
J. Phys. Chem. Lett. 2017, 8, 690 - 695. DOI: 10.1021/acs.jpclett.6b02869

T. Witt, M. Häußler, S. Mecking*:
No Strain, No Gain? Enzymatic Ring-Opening Polymerization of Strainless Aliphatic Macrolactones.
Macromol. Rapid Commun. 2017, 38, 1600638. DOI: 10.1002/marc.201600638

2016

A. Godin, I. Göttker-Schnetmann, S. Mecking*:
Nanocrystal Formation in Aqueous Insertion Polymerization.
Macromolecules 2016, 49, 8825 - 8837.
DOI: 10.1021/acs.macromol.6b01974

R. Machatschek, P. Ortmann, R. Reiter, S. Mecking, G. Reiter*:
Assembling semiconducting molecules by covalent attachment to a lamellar crystalline polymer substrate.
Beilstein J. Nanotechnol. 2016, 7, 784 - 798. DOI: 10.3762/bjnano.7.70

V. Goldbach, L. Falivene, L. Caporaso*, L. Cavallo, S. Mecking*:
Single-Step Access to Long-Chain α,ω-Dicarboxylic Acids by Isomerizing Hydroxycarbonylation of Unsaturated Fatty Acids.
ACS Catal. 2016, 6, 8229 - 8238. DOI: 10.1021/acscatal.6b02622

A. Godin, S. Mecking*:
Aqueous Dispersions of Multiphase Polyolefin Particles.
Macromolecules 2016, 49, 8296 - 8305. DOI: 10.1021/acs.macromol.6b01818

Z. Jian, L. Falivene, G. Boffa, S. Ortega Sánchez, L. Caporaso*, A. Grassi, S. Mecking*:
Direct Synthesis of Telechelic Polyethylene by Selective Insertion Polymerization.
Angew. Chem. Int. Ed. 2016, 55, 14378 - 14383. DOI: 10.1002/anie.201607754

H. Leicht, S. Huber, I. Göttker-Schnetmann, S. Mecking*:
Allylboration as a Versatile Tool for the In-Situ Post-Polymerization Functionalization of 1,4-cis-Poly(butadiene).
Polym. Chem. 2016, 7, 7195 - 7198. DOI: 10.1039/C6PY01388K

F. Werschler, C. Hinz, F. Froning, P. Gumbsheimer, J. Haase, C. Negele, T. de Roo, S. Mecking, A. Leitenstorfer, D. Seletskiy*:
Coupling of Excitons and Discrete Acoustic Phonons in Vibrationally Isolated Quantum Emitters.
Nano Lett. 2016, 16, 5861 - 5865. DOI: 10.1021/acs.nanolett.6b02667

T. de Roo, S. Huber, S. Mecking*:
CdSe/CdS-Conjugated Polymer Core-Shell Hybrid Nanoparticles by a Grafting-From Approach.
ACS Macro Lett. 2016, 5, 786 - 789. DOI: 10.1021/acsmacrolett.6b00323

Z. Jian, S. Mecking*:
Insertion Polymerization of Divinyl Formal.
Macromolecules 2016, 49, 4395 - 4403. DOI: 10.1021/acs.macromol.6b00983

H. Leicht, I. Göttker gen. Schnetmann, S. Mecking*:
Stereoselective Copolymerization of Butadiene and Functionalized 1,3-Dienes.
ACS Macro Lett. 2016, 5, 777 - 780. DOI: 10.1021/acsmacrolett.6b00321

Z. Jian, S. Mecking*:
Short-Chain Branched Polar-Functionalized Linear Polyethylene via "Tandem Catalysis".
Macromolecules 2016, 49, 4057 - 4066. DOI: 10.1021/acs.macromol.6b00581

Z. Jian, H. Leicht, S. Mecking*:
Direct Synthesis of Imidazolium-Functional Polyethylene by Insertion Copolymerization.
Macromol. Rapid Commun. 2016, 37, 934 - 938. DOI: 10.1002/marc.201600073

F. Stempfle, P. Ortmann, S. Mecking*:
Long-Chain Aliphatic Polymers to Bridge the Gap between Semicrystalline Polyolefins and Traditional Polycondensates.
Chem. Rev. 2016, 116, 4597 - 4641. DOI: 10.1021/acs.chemrev.5b00705

B. S. Rajput, U. Chander, K. Arole, F. Stempfle, S. K. Menon, S. Mecking, S. H. Chikkali*:
Synthesis of Renewable Copolyacetals with Tuneable Degradation.
Macromol. Chem. Phys. 2016, 217, 1396 - 1410. DOI: 10.1002/macp.201600071

N. Schuster, T. Rünzi, S. Mecking*:
Reactivity of Functionalized Vinyl Monomers in Insertion Copolymerization.
Macromolecules 2016, 49, 1172 - 1179. DOI: 10.1021/acs.macromol.5b02749

2015

C. Hintze, F. Schütze, M. Drescher*, S. Mecking*:
Probing of Chain Conformations in Conjugated Polymer Nanoparticles by Electron Spin Resonance Spectroscopy.
Phys. Chem. Chem. Phys. 2015, 17, 32289 - 32296. DOI: 10.1039/C5CP05749C

F. Ölscher, I. Göttker gen. Schnetmann, V. Monteil, S. Mecking*:
Role of Radical Species in Salicylaldiminato Ni(II) Mediated Polymer Chain Growth: A Case Study for the Migratory Insertion Polymerization of Ethylene in the Presence of MMA.
J. Am. Chem. Soc. 2015, 137, 14819 - 14828. DOI: 10.1021/jacs.5b08612

Z. Jian, S. Mecking*:
Insertion Homo- and Co-Polymerization of Diallyl Ether.
Angew. Chem. Int. Ed. 2015, 54, 15845 - 15849. DOI: 10.1002/anie.201508930
Angew. Chem. 2015, 127, 16071 - 16075. DOI: 10.1002/ange.201508930

F. Stempfle, B. Schemmer, A.-L. Oechsle, S. Mecking*:
Thermoplastic Polyester Elastomers based on Long-Chain Crystallizable Aliphatic Hard Segments.
Polym. Chem. 2015, 6, 7133 - 7137. DOI: 10.1039/C5PY01209K

V. Goldbach, P. Roesle, S. Mecking*:
Catalytic Isomerizing ω-Functionalization of Fatty Acids.
ACS Catal. 2015, 5, 5951 - 5972. DOI: 10.1021/acscatal.5b01508

T. Witt, F. Stempfle, P. Roesle, M. Häußler, S. Mecking*:
Unsymmetrical α,ω-Difunctionalized Long-Chain Compounds via Full Molecular Incorporation of Fatty Acids.
ACS Catal. 2015, 5, 4519 - 4529. DOI: 10.1021/acscatal.5b00825

P. Ortmann, F. P. Wimmer, S. Mecking*:
Long-Spaced Polyketones from ADMET Copolymerizations as Ideal Models for Ethylene/CO Copolymers.
ACS Macro Lett. 2015, 4, 704 - 707. DOI: 10.1021/acsmacrolett.5b00324

F. Schütze, M. Krumova, S. Mecking*:
Size Control of Spherical and Anisotropic Fluorescent Polymer Nanoparticles via Precise Rigid Molecules.
Macromolecules 2015, 48, 3900 - 3906. DOI: 10.1021/acs.macromol.5b00591

Z. Jian, M. C. Baier, S. Mecking*:
Suppression of Chain Transfer in Catalytic Acrylate Polymerization via Rapid and Selective Secondary Insertion.
J. Am. Chem. Soc. 2015, 137, 2836 - 2839. DOI: 10.1021/jacs.5b00179

P. Ortmann, T. Lemke, S. Mecking*:
Long-Spaced Polyamides: Elucidating the Gap between Polyethylene Crystallinity and Hydrogen Bonding.
Macromolecules 2015, 48, 1463 - 1472. DOI: 10.1021/acs.macromol.5b00060

C. S. Fischer, C. Jenewein, S. Mecking*:
Conjugated Star Polymers from Multidirectional Suzuki-Miyaura Polymerization for Live Cell Imaging.
Macromolecules 2015, 48, 483 - 491. DOI: 10.1021/ma502294n

V. Knittel, M. Fischer, T. de Roo, S. Mecking, A. Leitenstorfer, D. Brida*:
Nonlinear Photoluminescence Spectrum of Single Gold Nanostructures.
ACS Nano 2015, 9, 894 - 900. DOI: 10.1021/nn5066233

B. Zhang, J. Chen, M. C. Baier, S. Mecking, R. Reiter, R. Mülhaupt, G. Reiter*:
Molecular Weight Dependent Changes in Morphology of Solution Grown Polyethylene Single Crystals.
Macromol. Rapid Commun. 2015, 36, 181 - 189.
DOI: 10.1002/marc.201400433
_{Special Issue: Dedicated to Rolf Mülhaupt on the Occasion of his 60^th Birthday.}

B. Zhang, J. Chen, H. Zhang, M. C. Baier, S. Mecking, R. Reiter, R. Mülhaupt, G. Reiter*:
Annealing-Induced Periodic Patterns in Solution Grown Polymer Single Crystals.
RSC Advances 2015, 5, 12974 - 12980. DOI: 10.1039/C4RA10563J
_{Special Issue: Dedicated to Rolf Mülhaupt on the Occasion of his 60^th Birthday.}
T. Rünzi, M. C. Baier, C. Negele, M. Krumova, S. Mecking*:
Nanocomposites of Phosphonic Acid-Functionalized Polyethylenes with Inorganic Quantum Dots.
Macromol. Rapid Commun. 2015, 36, 165 - 173. DOI: 10.1002/marc.201400441

Z. Jian, L. Falivene, P. Wucher, P. Roesle, L. Caporaso, L. Cavallo, I. Göttker-Schnetmann, S. Mecking*:
Insights into Functional Group Tolerant Polymerization Catalysis with Phosphine-Sulfonamide Palladium(II) Complexes.
Chem. Eur. J. 2015, 21, 2062 - 2075. DOI: 10.1002/chem.201404856

2014

P. Roesle, L. Caporaso*, M. Schnitte, V. Goldbach, L. Cavallo, S. Mecking*:
A Comprehensive Mechanistic Picture of the Isomerizing Alkoxycarbonylation of Plant Oils.
J. Am. Chem. Soc. 2014, 136, 16871 - 16881. DOI: 10.1021/ja508447d

C. Jung, T. de Roo, S. Mecking*:
Conjugated Polymer Composite Nanoparticles by Rapid Mixing.
Macromol. Rapid Commun. 2014, 35, 2038 - 2042. DOI: 10.1002/marc.201400384

J. T. Christl, P. Roesle, F. Stempfle, G. Müller, L. Caporaso*, L. Cavallo, S. Mecking*:
Promotion of Selective Pathways in Isomerizing Functionalization of Plant Oils by Rigid Framework Substituents.
ChemSusChem. 2014, 7, 3491 - 3495. DOI: 10.1002/cssc.201402441

H. Busch, F. Stempfle, S. K. Heß, E. Grau, S. Mecking*:
Selective Isomerization-Carbonylation of a Terpene Trisubstituted Double Bond.
Green Chem. 2014, 16, 4541 - 4545. DOI: 10.1039/C4GC01233J

C. Jung, M. Krumova, S. Mecking*:
Hybrid Nanoparticles by Step-Growth Sonogashira Coupling in Disperse Systems.
Langmuir 2014, 30, 9905 - 9910. DOI: 10.1021/la502691b

P. Wucher, J. Schwaderer, S. Mecking*:
Solid-Supported Single-Component Pd(II) Catalysts for Polar Monomer Insertion Copolymerization.
ACS Catalysis 2014, 4, 2672 - 2679. DOI: 10.1021/cs5005954

R. Bärenwald, S. Goertlitz, R. Godehardt, A. Osichow, M. Krumova, S. Mecking, K. Saalwächer*:
Local Flips and Chain Motion in Polyethylene Crystallite: A Comparison of Melt-Crystallized Samples, Reactor Powders and Nanocrystals.
Macromolecules 2014, 47, 5163 - 5173. DOI: 10.1021/ma5020963

P. Roesle, F. Stempfle, S. K. Hess, J. Zimmerer, C. Río Bártulos, B. Lepetit, A. Eckert, P. G. Kroth*, S. Mecking*:
Synthetic Polyester from Algae Oil.
Angew. Chem. Int. Ed. 2014, 53, 6800 - 6804. DOI: 10.1002/anie.201403991
Angew. Chem. 2014, 126, 6918 - 6922. DOI: 10.1002/ange.201403991

Z. Jian, P. Wucher, S. Mecking*:
Heterocycle-Substituted Phosphinesulfonato Palladium(II) Complexes for Insertion Copolymerization of Methyl Acrylate.
Organometallics 2014, 33, 2879 - 2888. DOI: 10.1021/om500400a

A. Tchernook, M. Krumova, F. J. Tölle, R. Mülhaupt, S. Mecking*:
Composites from Aqueous Polyethylene Nanocrystal/Graphene Dispersions.
Macromolecules 2014, 47, 3017 - 3021. DOI: 10.1021/ma500394r

M. C. Baier, M. A. Zuideveld, S. Mecking*:
Post-Metallocenes in the Industrial Production of Polyolefins.
Angew. Chem. Int. Ed. 2014, 53, 9722 - 9744. DOI: 10.1002/anie.201400799
Angew. Chem. 2014, 126, 9878 - 9902. DOI: 10.1002/ange.201400799

F. Stempfle, B.S. Ritter, R. Mülhaupt*, S. Mecking*:
Long-Chain Aliphatic Polyesters from Plant Oils for Injection Molding, Film Extrusion and Electrospinning.
Green Chem. 2014, 16, 2008 - 2014. DOI: 10.1039/C4GC00114A

P. Ortmann, I. Heckler, S. Mecking*:
Physical Properties and Hydrolytic Degradability of Polyethylene-like Polyacetals and Polycarbonates.
Green Chem. 2014, 16, 1816 - 1827. DOI: 10.1039/C3GC42592D

T. de Roo, J. Haase, J. Keller, C. Hinz, M. Schmid, D. V. Seletskiy, H. Cölfen, A. Leitenstorfer, S. Mecking*:
A Direct Approach to Organic/Inorganic Semiconductor Hybrid Particles via Functionalized Polyfluorene Ligands.
Adv. Funct. Mater. 2014, 24, 2714 - 2719. DOI: 10.1002/adfm.201304036

T. Wiedemann, G. Voit, A. Tchernook, P. Roesle, I. Göttker-Schnetmann, S. Mecking*:
Monofunctional Hyperbranched Ethylene Oligomers.
J. Am. Chem. Soc. 2014, 136, 2078 - 2085. DOI: 10.1021/ja411945n

T. Rünzi, S. Mecking*:
Saturated polar-substituted Polyethylene Elastomers from Insertion Polymerization.
Adv. Funct. Mater. 2014, 24, 387 - 395. DOI: 10.1002/adfm.201301755

2013

B. Scheinhardt, J. Trzaskowski, M. C. Baier, B. Stempfle, A. Oppermann, D. Wöll*, S. Mecking*:
Anisotropic Polyethylene Nanocrystals Labeled with a Single Fluorescent Dye Molecule: Towards Monitoring of Nanoparticle Orientation.
Macromolecules 2013, 46, 7902 - 7910. DOI: 10.1021/ma401828k

B. Neuwald, L. Falivene, L. Caporaso*, L. Cavallo, S. Mecking*:
Exploring Electronic and Steric Effects on the Insertion and Polymerization Reactivity of Phosphinesulfonato Pd(II) catalysts.
Chem. Eur. J. 2013, 19, 17773 - 17788. DOI: 10.1002/chem.201301365

A. Osichow, I. Göttker-Schnetmann, S. Mecking*:
Role of Electron-Withdrawing Remote Substituents in Neutral Nickel(II) Polymerization Catalysts.
Organometallics 2013, 32, 5239 - 5242. DOI: 10.1021/om400757f

M. Dill, M. C. Baier, S. Mecking, D. Wöll*:
Enhanced Accuracy of Single Molecule Diffusion Measurements with a Photocleavable FRET Dyad.
Angew. Chem. Int. Ed. 2013, 52, 12435 - 12438. DOI: 10.1002/anie.201303658
Angew. Chem. 2013, 125, 12662 - 12666. DOI: 10.1002/ange.201303658

P. Ortmann, S. Mecking*:
Long-Spaced Aliphatic Polyesters.
Macromolecules 2013, 46, 7213 - 7218. DOI: 10.1021/ma401305u

P. Wucher, V. Goldbach, S. Mecking*:
Electronic Influences in Phosphine Sulfonato Palladium(II) Polymerization Catalysts.
Organometallics 2013, 32, 4516 - 4522. DOI: 10.1021/om400297x

A. Osichow, C. Rabe, K. Vogtt, T. Narayanan, L. Harnau, M. Drechsler, M. Ballauff*, S. Mecking*:
Ideal Polyethylene Nanocrystals.
J. Am. Chem. Soc. 2013, 135, 11645 - 11650. DOI: 10.1021/ja4052334

I. E. Soshnikov, N. V. Semikolenova, V. A. Zakharov, H. M. Möller, F. Ölscher, A. Osichow, I. Göttker-Schnetmann, S. Mecking*, E. P. Talsi, K. P. Bryliakov*:
Formation and Evolution of Chain Propagating Species Upon Ethylene Polymerization with Neutral Salicylaldiminato Nickel(II) Catalysts.
Chem. Eur. J. 2013, 19, 11409 - 11417. DOI: 10.1002/chem.201301037

T. Witt, S. Mecking*:
Large-Ring Lactones from Plant Oils.
Green Chem. 2013, 15, 2361 - 2364. DOI: 10.1039/C3GC40905H

J. T. Christl, P. Roesle, F. Stempfle, P. Wucher, I. Göttker-Schnetmann, G. Müller*, S. Mecking*:
Catalyst Activity and Selectivity in the Isomerizing Alkoxycarbonylation of Methyl Oleate.
Chem. Eur. J. 2013, 19, 17131 - 17140. DOI: 10.1002/chem.201301124

C. Negele, J. Haase, A. Budweg, A. Leitenstorfer*, S. Mecking*:
Stable Single Photon Emission by Quantum Dot/Polymer Hybrid Particles.
Macromol. Rapid Commun. 2013, 34, 1145 - 1150. DOI: 10.1002/marc.201300327

A. Nakamura, T. Anselment, J. Claverie, B. Goodall, R. Jordan, S. Mecking, B. Rieger, A. Sen, P.W.N.M. van Leeuwen, K. Nozaki*:
Ortho-Phosphinobenzenesulfonate: A Superb Ligand for Palladium-Catalyzed Coordination-Insertion Copolymerization of Polar Vinyl Monomers.
Acc. Chem. Res. 2013, 46, 1439 - 1449. DOI: 10.1021/ar300256h

E. Grau, S. Mecking*:
Polyterpenes by Ring Opening Metathesis Polymerization of Caryophyllene and Humulene.
Green Chem. 2013, 15, 1112 - 1115. DOI: 10.1039/C3GC40300A
_{Selected for issue cover by the editors.}

H. Leicht, I. Göttker-Schnetmann, S. Mecking*:
Incorporation of Vinyl Chloride in Insertion Polymerization.
Angew. Chem. Int. Ed. 2013, 52, 3963 - 3966.
DOI: 10.1002/anie.201209724
Angew. Chem. 2013, 125, 4055 - 4058. DOI: 10.1002/ange.201209724
_{Selected as very important paper by the editors, chosen for issue cover.}
P. Ortmann, J. Trzaskowski, M. Krumova, S. Mecking*:
Precise Microstructure Self-Stabilized Polymer Nanocrystals.
ACS Macro Letters 2013, 2, 125 - 127. DOI: 10.1021/mz300606n

C. S. Fischer, M. C. Baier, S. Mecking*:
Enhanced Brightness Emission-Tuned Nanoparticles from Heterodifunctional Polyfluorene Building Blocks.
J. Am. Chem. Soc. 2013, 135, 1148 - 1154. DOI: 10.1021/ja311497e

B. Neuwald, L. Caporaso*, L. Cavallo, S. Mecking*:
Concepts for Stereoselective Acrylate Insertion.
J. Am. Chem. Soc. 2013, 135, 1026 - 1036. DOI: 10.1021/ja3101787

Lisa Hoelting, B. Scheinhardt, O. Bondarenko, S. Schildknecht, M. Kapitza, V. Tanavde, B. Tan, Q. Y. Lee, S. Mecking, M. Leist, S. Kadereit*:
A 3-Dimensional Human Embryonic Stem Cell (hESC)-Derived Model to Detect Developmental Neurotoxicity of Nanoparticles.
Arch. Toxicol. 2013, 87, 721 - 733. DOI: 10.1007/s00204-012-0984-2

F. Stempfle, P. Ortmann, S. Mecking*:
Which Polyesters can Mimic Polyethylene?
Macromol. Rapid Commun. 2013, 34, 47 - 50. DOI: 10.1002/marc.201200611

2012

P. Wucher, P. Roesle, L. Falivene, L. Cavallo, L. Caporaso*, I. Göttker-Schnetmann, S. Mecking*:
Controlled Acrylate Insertion Regioselectivity in Diazaphospholidine-Sulfonato Palladium(II) Complexes.
Organometallics 2012, 31, 8505 - 8515. DOI: 10.1021/om300755j

T. Rünzi, U. Tritschler, P. Roesle, I. Göttker-Schnetmann, H. M. Möller, L. Caporaso*, A. Poater, L. Cavallo, S. Mecking*:
Activation and Deactivation of Neutral Palladium(II) Phosphinesulfonato Polymerization Catalysts.
Organometallics 2012, 31, 8388 - 8406. DOI: 10.1021/om300969d

F. Stemple, P. Roesle, S. Mecking*:
Long-Chain Polyesters via Chemical Catalytic Conversions of Fatty Acid Esters (Ed.: R. Gross, P. B. Smith).
ACS Symp. Series 1105 Biobased Monomers, Polymers and Materials, 2012, pp. 151 - 163. DOI: 10.1021/bk-2012-1105.ch010

C. Negele, J. Haase, A. Leitenstorfer*, S. Mecking*:
Polyfluorene Nanoparticles and Quantum Dot Hybrids via Miniemulsion Polymerization.
ACS Macro Letters 2012, 1, 1343 - 1346. DOI: 10.1021/mz300427d

P. Roesle, C. J. Dürr, H. M. Möller*, L. Cavallo, L. Caporaso*, S. Mecking*:
Mechanistic Features of Isomerizing Alkoxycarbonylation of Methyl Oleate.
J. Am. Chem. Soc. 2012, 134, 17696 - 17703. DOI: 10.1021/ja307411p

J. Huber, C. Jung, S. Mecking*:
Nanoparticles of Low Optical Band Gap Conjugated Polymers.
Macromolecules 2012, 45, 7799 - 7805. DOI: 10.1021/ma3013459

J. Trzaskowski, C. Rabe, K. Vogtt, M. Krumova, G. Goerigk, M. Ballauf*, S. Mecking*:
Anisotropic Nanoparticles of Precise Microstructure Polyolefins.
Chem. Commun. 2012, 48, 9153 - 9155. DOI: 10.1039/C2CC32834H

B. Neuwald, F. Ölscher, I. Göttker-Schnetmann, S. Mecking*:
Limits of Activity: Weakly Coordinating Ligands in Arylphosphinesulfonato Pd(II) Polymerization Catalysts.
Organometallics 2012, 31, 3128 - 3137. DOI: 10.1021/om3000339

S. Chikkali, F. Stempfle, S. Mecking*:
Long-Chain Polyacetals from Plant Oils.
Macromol. Rapid Commun. 2012, 33, 1126 - 1129.
DOI: 10.1002/marc.201200226
_{Chosen for issue cover; highlighted in Materials View.}

S. Chikkali, S. Mecking*:
Refining of Plant Oils to Chemicals by Olefin Metethesis.
Angew. Chem. Int. Ed. 2012, 51, 5802 - 5808. DOI: 10.1002/anie.201107645
Angew. Chem. 2012, 124, 5902 - 5909. DOI: 10.1002/ange.201107645

N. Basu, A. Osichow, S. Mecking, G. Reiter*:
Morphological Changes During Annealing of Polyethylene Nanocrystals.
Eur. Phys. J. E - Soft Matter & Biological Physics 2012, 35, 18.
DOI: 10.1140/epje/i2012-12018-9

F. Schütze, B. Stempfle, C. Jüngst, D. Wöll, A. Zumbusch, S. Mecking*:
Fluorescent Conjugated Block Copolymer Nanoparticles by Controlled Mixing.
Chem. Commun. 2012, 48, 2104 - 2106. DOI: 10.1039/C2CC17066C

T. Friedberger, P. Wucher, S. Mecking*:
Mechanistic Insights into Polar Monomer Insertion Polymerization from Acrylamides.
J. Am. Chem. Soc. 2012, 134, 1010 - 1018. DOI: 10.1021/ja207110

B. Flier, M. Baier, J. Huber, K. Müllen, S. Mecking, A. Zumbusch, D. Wöll*:
Heterogeneous Diffusion in Thin Polymer Films as observed by High-Temperature Single Molecule Fluorescence Microscopy.
J. Am. Chem. Soc. 2012, 134, 480 - 488. DOI: 10.1021/ja208581r

M. R. L. Furst, R. Le Goff, D. Quinzler, S. Mecking, C. H. Botting, D. J. Cole-Hamilton*:
Polymer Precursors from Catalytic Reactions of Natural Oils.
Green Chem. 2012, 14, 472 - 477. DOI: 10.1039/C1GC16094J

H. M. Möller*, M. C. Baier, S. Mecking, E. P. Talsi, K. P. Bryliakov*:
The Origin of Living Polymerization with an o-Fluorinated Catalyst: NMR-Spectroscopic Characterization of Chain-Propagating Species.
Chem. Eur. J. 2012, 18, 848 - 856. DOI: 10.1002/chem.201102408

2011

J. Huber, B. Scheinhardt, T. Geldhauser, J. Boneberg, S. Mecking*:
Polymerization Catalyst Laser-Interference Patterning.
Angew. Chem. Int. Ed. 2011, 50, 9665 - 9667.
DOI: 10.1002/anie.201105346
Angew. Chem. 2011, 123, 9839 - 9841. DOI: 10.1002/ange.201103990
_{Selected as very important paper by the editors, chosen for issue cover.}

J. Trzaskowski, D. Quinzler, C. Bährle, S. Mecking*:
Aliphatic Long-Chain C20 Polyesters from Olefin Metathesis.
Macromol. Rapid Commun. 2011, 32, 1352 - 1356.
DOI: 10.1002/marc.201100319
_{Chosen for issue cover.}

M. Ballauff,* C. Rochette, S. Rosenfeldt, K. Henzler, F. Polzer, S. Mecking, Stefan, Q. Tong, M. Drechsler, N. Theyencheri, L. Harnau*:
Annealing of Single Lamella Nanoparticles of Polyethylene.
Macromolecules 2011, 44, 4845 - 4851. DOI: 10.1021/ma2003213

F. Stempfle, D. Quinzler, I. Heckler, S. Mecking*:
Long-Chain Linear C19 and C23 Monomers and Polycondensates from Unsaturated Fatty Acid Esters.
Macromolecules 2011, 44, 4159 - 4166. DOI: 10.1021/ma200627e

P. Wucher, L. Caporaso*, P. Roesle, F. Ragone, L. Cavallo, S. Mecking*, I. Göttker-Schnetmann*:
Breaking the regioselectivity rule for acrylate insertion in the Mizoroki-Heck reaction.
Proc. Natl. Acad. Sci. 2011, 108, 8955 - 8959. DOI: 10.1073/pnas.1101497108

B.M.I. Flier, M.C. Baier, J. Huber, K. Müllen, S. Mecking, A. Zumbusch, D. Wöll*:
Single Molecule Fluorescence Microscopy Investigations on Heterogeneity of Translational Diffusion in Thin Polymer Films.
Phys. Chem. Chem. Phys. 2011, 13, 1770 - 1775. DOI: 10.1039/C0CP01801E

2010

T. Rünzi, D. Fröhlich, S. Mecking*:
Direct Synthesis of Ethylene-Acrylic Acid Copolymers by Insertion Polymerization.
J. Am. Chem. Soc. 2010, 132, 17690 - 17691. DOI: 10.1021/ja109194r

T. Rünzi, D. Guironnet, I. Göttker-Schnetmann, S. Mecking*:
Reactivity of Methacrylates in Insertion Polymerization.
J. Am. Chem. Soc. 2010, 132, 16623 - 16630. DOI: 10.1021/ja107538r

J. Pecher, J. Huber, M. Winterhalder, A. Zumbusch*, S. Mecking*:
Tailor-Made Conjugated Polymer Nanoparticles for Multicolor and Multiphoton Cell Imaging.
Biomacromolecules 2010, 11, 2776 - 2780. DOI: 10.1021/bm100854a

K. Bryliakov*, E. P. Talsi, H. M. Möller, M. C. Baier, S. Mecking*:
Noncovalent Interactions in o-Fluorinated Post-Titanocene Living Ethylene Polymerization Catalysts.
Organometallics 2010, 29, 4428 - 4430. DOI: 10.1021/om100729y

J. Huber, S. Mecking*:
Aqueous Poly(aryl acetylene) Dispersions.
Macromolecules 2010, 43, 8718 - 8723. DOI: 10.1021/ma1013572

B. Korthals, M. C. Morant-Minana, M. Schmid, S. Mecking*:
Functionalization of Polymer Nanoparticles by Thiol-Ene Addition.
Macromolecules 2010, 43, 8071 - 8078. DOI: 10.1021/ma100966w

J. Pecher, S. Mecking*:
Nanoparticles of Conjugated Polymers (invited contribution).
Chem. Rev. 2010, 110, 6260 - 6279. DOI: 10.1021/cr100132y

J. Urbano, B. Korthals, M. M. Diaz-Requejo*, P. J. Perez*, S. Mecking*:
Catalytic Cyclopropanation of Polybutadienes.
J. Polym. Sci. A: Polym. Chem. 2010, 48, 4439 - 4444. DOI: 10.1002/pola.24231

A. Osichow, S. Mecking*:
Alkoxycarbonylation of Ethylene with Cellulose in Ionic Liquids.
Chem. Commun. 2010, 46, 4980 - 4981. DOI: 10.1039/C0CC00606H

D. Quinzler, S. Mecking*:
Linear Semicrystalline Polyesters from Fatty Acids by Complete Feedstock Molecule Utilization.
Angew. Chem. Int. Ed. 2010, 49, 4306 - 4308. DOI: 10.1002/anie.201001510
Angew. Chem. 2010, 122, 4402 - 440. DOI: 10.1002/ange.201001510

Nature's Polyethylene.
Angew. Chem. Int. Ed. 2010, 49, 8564 - 8566. DOI: 10.1002/anie.201002593
Angew. Chem. 2010, 122, 8744 - 8746. DOI: 10.1002/ange.201002593
_{Selected as Very Important Paper by the Editors Highlighted in D.J. Cole-Hamilton.}

D. Guironnet, L. Caporaso*, B. Neuwald, I. Göttker-Schnetmann, L. Cavallo, S. Mecking*:
Mechanistic Insights on Acrylate Insertion Polymerisation.
J. Am. Chem. Soc. 2010, 132, 4418 - 4426. DOI: 10.1021/ja111255e

S.-M. Yu, U. Tritschler, I. Göttker-Schnetmann, S. Mecking*:
Zirconium Enolatoimine Complexes in Olefin Polymerization.
Dalton Trans. 2010, 3, 4612 - 4618. DOI: 10.1039/B916289E

C. Bouilhac, T. Rünzi, S. Mecking*:
Catalytic Copolymerization of Ethylene with Vinyl Sulfones.
Macromolecules 2010, 43, 3589 - 3590. DOI: 10.1021/ma100237s

2009

M.C. Baier, J. Huber, S. Mecking*:
Fluorescent Conjugated Polymer Nanoparticles by Polymerization in Miniemulsion.
J. Am. Chem. Soc. 2009, 131, 14267 - 14273. DOI: 10.1021/ja905077c

D. Quinzler, S. Mecking*:
Renewable Resource-based Poly(dodecyloate) by Carbonylation Polymerization.
Chem. Commun. 2009, 5400 - 5402. DOI: 10.1039/B912294J
_{Featured in Highlights in Chemical Science and Chemistry World.}
Q. Tong, S. Mecking*:
Submicron Films Prepared from Aqueous Dispersions of Nanoscale Polymer Crystals.
J. Polym. Sci. A: Polym. Chem. 2009, 47, 6420 - 6432. DOI: 10.1002/pola.23682

D. Guironnet, T. Friedberger, S. Mecking*:
Ethylene Polymerization in Supercritical Carbon Dioxide with Binuclear Nickel(II) Catalysts.
Dalton Trans. 2009, 8929 - 8934. DOI: 10.1039/B912883B

D. Guironnet, I. Göttker-Schnetmann, S. Mecking*:
Catalytic Polymerization in Dense CO₂ to Controlled Microstructure Polyethylenes.
Macromolecules 2009, 42, 8157 - 8164. DOI: 10.1021/ma901397q

B. Korthals, M.C. Morant-Minana, C. Hohberger, S. Mecking*:
Conveniently Accessible Polymer Nanoparticles of Adjustable Polarity.
Langmuir 2009, 25, 10554 - 10557. DOI: 10.1021/la9013224

D. Zhang, D. Guironnet, I. Göttker-Schnetmann, S. Mecking*:
Water-Soluble Complexes [(k²-P,O-Phosphinesulfonato)PdMe(L)] and their Catalytic Properties.
Organometallics 2009, 28, 4072 - 4078. DOI: 10.1021/om9003225

A. Berkefeld, H. Möller, S. Mecking*:
Unusual Reactivity of N,N,N',N'-Tetramethylethylenediamine Coordinated Neutral Ni(II) Polymerization Catalysts.
Organometallics 2009, 28, 4048 - 4055. DOI: 10.1021/om900198c

A. Berkefeld, M. Drexler, H. Möller, S. Mecking*:
Mechanistic Insights on the Copolymerization of Polar Vinyl Monomers with Neutral Ni(II) Catalysts.
J. Am. Chem. Soc. 2009, 131, 12613 - 12622. DOI: 10.1021/ja901360b
_{Selected for issue cover by the editors.}

S.-M. Yu, S. Mecking*:
Variable Crystallinity Polyethylene Nanoparticles.
Macromolecules 2009, 42, 3669 - 3673. DOI: 10.1021/ma9003665

A. Berkefeld, S. Mecking*:
Deactivation Pathways of Neutral Ni(II) Polymerization Catalysts.
J. Am. Chem. Soc. 2009, 131, 1565 - 1574. DOI: 10.1021/ja808855v

D. Guironnet, P. Roesle, T. Rünzi, I. Göttker-Schnetmann, S. Mecking*:
Insertion Polymerization of Acrylate.
J. Am. Chem. Soc. 2009, 131, 422 - 423. DOI: 10.1021/ja808017n

2008

A. Amgoune, M. Krumova, S. Mecking*:
Nanoparticle-Supported Molecular Polymerization Catalysts.
Macromolecules 2008, 41, 8388 - 8396. DOI: 10.1021/ma801995g

B. Korthals, A. Berkefeld, M. Ahlmann, S. Mecking*:
Catalytic Polymerization of Butadiene in Aqueous Systems with Cationic Nickel(II) Complexes.
Macromolecules 2008, 41, 8332 - 8338. DOI: 10.1021/ma8016579

S.-M. Yu, S. Mecking*:
Extremely Narrow-Dispersed High Molecular Weight Polyethylene from Living Polymerization at Elevated Temperatures with o-F Substituted Ti Enolatoimines.
J. Am. Chem. Soc. 2008, 130, 13204 - 13205. DOI: 10.1021/ja805304p

D. Guironnet, T. Rünzi, I. Göttker-Schnetmann, S. Mecking*:
Control of Molecular Weight in Ni(II)-Catalyzed Polymerization via the Reaction Medium.
Chem. Commun. 2008, 4965 - 4967. DOI: 10.1039/B811888D

Q. Tong, M. Krumova, S. Mecking*:
Crystalline Polymer Ultrathin Films from Mesoscopic Precursors.
Angew. Chem. Int. Ed. 2008, 47, 4509 - 4511. DOI: 10.1002/anie.200801028
Angew. Chem. 2008, 120, 4585 - 4587. DOI: 10.1002/ange.200801028

A. Berkefeld, S. Mecking*:
Coordination Copolymerization of Polar Vinyl Monomers H₂C=CHX.
Angew. Chem. Int. Ed. 2008, 47, 2538 - 2542. DOI: 10.1002/anie.200704642
Angew. Chem. 2008, 120, 2572 - 2576. DOI: 10.1002/ange.200704642

Y. Gao, S. Reischmann, J. Huber, T. Hanke, R. Bratschitsch, A. Leitenstorfer, S. Mecking*:
Encapsulating of Single Quantum Dots into Polymer Particles.
Coll. Polym. Sci. 2008, 286, 1329. DOI: 10.1007/s00396-008-1899-6

P. Wehrmann, S. Mecking*:
Highly Active Binuclear Neutral Nickel(II) Catalysts Affording High Molecular Weight Polyethylene
Organometallics 2008, 27, 1399 - 1408. DOI: 10.1021/om700942z

Q. Tong, M. Krumova, I. Göttker gen. Schnetmann, S. Mecking*:
Crystallization as a Means for the Switching of Nanoscale Containers.
Langmuir 2008, 24, 2341 - 2347. DOI: 10.1021/la702500n

J. Huber, A. Amgoune, S. Mecking*:
Patterning of Polymer on a Substrate via Ink-Jet Printing of a Coordination Polymerization Catalyst.
Adv. Mater. 2008, 20, 1978 - 1981. DOI: 10.1002/adma.200702702

2007

J. Pecher, S. Mecking*:
Nanoparticles from Step-Growth Coordination Polymerization.
Macromolecules 2007, 40, 7733 - 7735. DOI: 10.1021/ma702048t

S. Moisan, V. Martinez, P. Weisbecker, F. Cansell, S. Mecking*, C. Aymonier*:
A General Approach for the Synthesis of Organic-Inorganic Hybrid Nanoparticles Mediated by Supercritical CO₂.
J. Am. Chem. Soc. 2007, 129, 10602 - 10606. DOI: 10.1021/ja074069j

C. H. M. Weber, A. Chiche, G. Krausch*, S. Rosenfeldt, M. Ballauff*, L. Harnau, I. Göttker gen. Schnetmann, Q. Tong, S. Mecking*:
Single Lamella Nanoparticles of Polyethylene.
Nano Lett. 2007, 7, 2024 - 2029. DOI: 10.1021/nl070859f

A. Bastero, I. Göttker-Schnetmann, C. Röhr, S. Mecking*:
Polymer Microstructure Control in Catalytic Polymerization Exclusively by Electronic Effects of Remote Substituents.
Adv. Synth. Catal. 2007, 349, 2307 - 2316. DOI: 10.1002/adsc.200700127

L. Antonietti née Tuchbreiter, S. Mecking*:
Hydroformylation with Dendritic Polymer-Stabilized Rhodium Colloids as Catalyst Precursors.
Macromol. Chem. Phys. 2007, 208, 1688 - 1693. DOI: 10.1002/macp.200700198

C. H. M. Weber, A. Chiche, G. Krausch*, S. Rosenfeld, M. Ballauff*, I. Göttker-Schnetmann, Q. Tong, S. Mecking*, L. Harnau*:
Single Lamella Crystals of Polyethylene Accessible by Catalytic Emulsion Polymerization.
Polym. Mat. Sci. Eng. 2007, 97, 133 - 134. KOPS

I. Göttker gen. Schnetmann, P. Wehrmann, C. Röhr, S. Mecking*:
Substituent Effects in (k²-N,O)-Salicylaldiminato Nickel(II)-Methyl Pyridine Polymerization Catalysts: Terphenyls Controlling Polyethylene Microstructures.
Organometallics 2007, 26, 2348 - 2362. DOI: 10.1021/om0611498

G. Korthals, I. Göttker gen. Schnetmann, S. Mecking*:
Nickel(II)-Methyl Complexes with Water-Soluble Ligands L [(salicylaldiminato-k²-N,O)NiMe(L)] and Their Catalytic Properties in Disperse Aqueous Systems.
Organometallics 2007, 26, 1311 - 1316. DOI: 10.1021/om0607191

J. Huber, S. Mecking*:
Aqueous Polyalkyne Dispersions.
Polym. Mat. Sci. Eng. 2007, 96, 306 - 307. KOPS

S.-M. Yu, A. Berkefeld , I. Göttker gen. Schnetmann, G. Müller, S. Mecking*:
Synthesis of Aqueous Polyethylene Dispersions with Electron-Deficient Neutral Nickel(II) Catalysts with Enolatoimine Ligands.
Macromolecules 2007, 40, 421 - 428. DOI: 10.1021/ma061804n

S. Mecking*:
Polymer Dispersions from Catalytic Polymerization in Aqueous Systems.
Coll. Polym. Sci. 2007, 285, 605 - 619. DOI: 10.1007/s00396-006-1587-3

2006

J. Huber, S. Mecking*:
Processing of Polyacetylene from Aqueous Nanoparticle Dispersions.
Angew. Chem. Int. Ed. 2006, 45, 6314 - 6317. DOI: 10.1002/anie.200601694
Angew. Chem. 2006, 118, 6462 - 6465. DOI: 10.1002/ange.200601694

P. Wehrmann, S. Mecking*:
Aqueous Dispersions of Polypropylene and Poly(1-butene) with Variable Microstructures formed with Neutral Ni(II)-Complexes.
Macromolecules 2006, 39, 5963 - 5964. DOI: 10.1021/ma061462l

P. Wehrmann, M. A. Zuideveld, R. Thomann, S. Mecking*:
Copolymerization of Ethylene with 1-Butene and Norbornene to Higher Molecular Weight Copolymers in Aqueous Emulsion.
Macromolecules 2006, 39, 5995 - 6002. DOI: 10.1021/ma060813t

A. Berkefeld, S. Mecking*:
Mechanistic Studies of Catalytic Polyethylene Chain Growth in the Presence of Water.
Angew. Chem. Int. Ed. 2006, 45, 6044 - 6046. DOI: 10.1002/anie.200601387
Angew. Chem. 2006, 118, 6190 - 6193. DOI: 10.1002/ange.200601387

I. Göttker gen. Schnetmann, B. Korthals, S. Mecking*:
Water-Soluble Salicylaldiminato Ni(II)-Methyl Complexes: Enhanced Dissociative Activation for Ethylene Polymerization with Unprecedented Nanoparticle Formation.
J. Am. Chem. Soc. 2006, 128, 7708 - 7709. DOI: 10.1021/ja0619962

A. Bastero, G. Francio, W. Leitner*, S. Mecking*:
Catalytic Ethylene Polymerization in Carbon Dioxide as a Reaction Medium with Soluble Nickel (II) Catalysts.
Chemistry - Eur. J. 2006, 12, 6110 - 6116. DOI: 10.1002/chem.200600499

V. Martinez, S. Mecking*, T. Taissing, M. Besnard, S. Moisan, F. Cansell, C. Aymonier*:
Dendritic Core-Shell Molecules Soluble in Supercritical Carbon Dioxide.
Macromolecules 2006, 39, 3978 - 3979. DOI: 10.1021/ma0607315

G. Noël, J. C. Röder, S. Dechert, H. Pritzkow, L. Bolk, S. Mecking, F. Meyer*:
Pyrazolate-Based Dinuclear a-Diimine-Type Palladium(II) and Nickel(II) Complexes - A Bimetallic Approach in Olefin Polymerisation.
Adv. Synth. Catal. 2006, 348, 887 - 897. DOI: 10.1002/adsc.200505457

V. Monteil, J. Stumbaum, R. Thomann, S. Mecking*:
Silica/Polyethylene Nanocomposite Particles from Catalytic Emulsion Polymerization.
Macromolecules 2006, 39, 2056 - 2062. DOI: 10.1021/ma052737k

S. Mecking*, V. Monteil, J. Huber, L. Kolb, P. Wehrmann:
Synthesis of Very Small Polymer Particles by Catalytic Polymerization.
Makromol. Symp. 2006, 236, 117 - 123. DOI: 10.1002/masy.200690044

2005

V. Monteil, P. Wehrmann, S. Mecking*:
A General Route to Very Small Polymer Particles with Controlled Microstructures.
J. Am. Chem. Soc. 2005, 127, 14568 - 14569. DOI: 10.1021/ja0558084

E. Schwab, S. Mecking*:
Recoverable Catalysts Non-covalently Bound to a Hyperbranched Polyelectrolyte.
Organometallics 2005, 24, 3758 - 3763. DOI: 10.1021/om050266k

E. Schwab, S. Mecking*:
Synthesis and Properties of Highly Branched Polycations with an Aliphatic Polyether Scaffold.
J. Polym. Sci. A, Polym. Chem. 2005, 43, 4609 - 4617. DOI: 10.1002/pola.20983

Multiphase Homogeneous Catalysis.
(Eds.: B. Cornils, W.A. Hermann, I. Horvath, W. Leitner, S. Mecking, H. Olivier-Bourbigou, D. Vogt), Wiley-VCH, 2005. DOI: 10.1002/9783527619597.ch1

I. H. Hristov, R. L. DeKock, G. D.W. Anderson, I. Göttker genannt Schnetmann, S. Mecking, T. Ziegler*:
Possible Side Reactions Due to Water in Emulsion Polymerization by Late Transition Metal Complexes. 1. Water Complexation and Hydrolysis of the Growing Chain.
Inorg. Chem. 2005, 44, 7806 - 7818. DOI: 10.1021/ic050501r

L. Antonietti, C. Aymonier, U. Schlotterbeck, V.M. Garamus, T. Maksimova, W. Richtering, S. Mecking*:
Core-Shell-Structured Highly Branched Poly(ethylenimineamide)s: Synthesis and Structure.
Macromolecules 2005, 38, 5914 - 5920. DOI: 10.1021/ma047458w

V. Monteil, A. Bastero, S. Mecking*:
1,2-Polybutadiene Latices by Catalytic Polymerization in Aqueous Emulsion.
Macromolecules 2005, 38, 5393 - 5399. DOI: 10.1021/ma050621i

M.M. Diaz-Requejo, P. Wehrmann, M.D. Leatherman, S. Trofimenko, S. Mecking, M. Brookhart, P.J. Perez*:
Controlled, Copper-Catalyzed Functionalization of Polyolefins.
Macromolecules 2005, 38, 4966 - 4969. DOI: 10.1021/ma050626f

R.L. De Kock, I.H. Hristov, G.D.W. Anderson, I. Göttker genannt Schnetmann, S. Mecking, T. Ziegler*:
Possible Side Reactions Due to Water in Emulsion Polymerization by Late Transition Metal Complexes II: Deactivation of the Catalyst by a Wacker-Type Reaction.
Organometallics 2005, 24, 2679 - 2687. DOI: 10.1021/om049059v

R. Sablong, J.I. van der Vlugt, R. Thomann, S. Mecking*, D. Vogt*:
Disperse Amphiphilic Submicron Particles as Non-Covalent Supports for Cationic Homogeneous Catalysts.
Adv. Synth. Catal. 2005, 347, 633 - 636. DOI: 10.1002/adsc.200404284

A. Bastero, S. Mecking*:
Synthesis of Submicrometer Particles of a Stereoregular Polyolefin by Catalysis in Aqueous Dispersion.
Macromolecules 2005, 38, 220 - 222. DOI: 10.1021/ma047649z

L. Kolb, V. Monteil, R. Thomann, S. Mecking*:
Aqueous Dispersions of Extraordinarily Small Polyethylene Nanoparticles.
Angew. Chem. Int. Ed. 2005, 44, 429 - 432. DOI: 10.1002/anie.200460455
Angew. Chem. 2005, 117, 433 - 436. DOI: 10.1002/ange.200460455

2004

M. A. Zuideveld, P. Wehrmann, C. Röhr, S. Mecking*:
Remote Substituents Controlling Catalytic Polymerization by Very Active and Robust Neutral Nickel(II) Complexes.
Angew. Chem. Int. Ed. 2004, 43, 869 - 873. DOI: 10.1002/anie.200352062
Angew. Chem. 2004, 116, 887 - 891. DOI: 10.1002/ange.200352062

S. Mecking:
Nature or Petrochemistry? - Biologically Degradable Materials.
Angew. Chem. Int. Ed. 2004, 43, 1078 - 1085. DOI: 10.1002/anie.200301655
Angew. Chem. 2004, 116, 1096 - 1104. DOI: 10.1002/ange.200301655

S. Mecking:
Catalytic Polymerization.
Aqueous Phase Organometallic Catalysis (Eds.: W. A. Herrmann, B. Cornils), Wiley-VCH, 2nd Edition, 2004, 576 - 592.

S. Mecking, E. Schwab:
Catalysis with Water-Soluble Polymer-bound Ligands in Aqueous Solution.
Aqueous Phase Organometallic Catalysis (Eds.: W. A. Herrmann, B. Cornils), Wiley-VCH, 2nd Edition, 2004, 699 - 705.

Ulf Schlotterbeck, Cyril Aymonier, Ralf Thomann, Herbert Hofmeister, Moniek Tromp, Walter Richtering, Stefan Mecking*:
Shape-Selective Synthesis of Palladium Nanoparticles Stabilized by Highly Branched Amphiphilic Polymers.
Adv. Funct. Mat. 2004, 14, 999 - 1004. DOI: 10.1002/adfm.200400053

V. M. Garamus, T. V. Maksimova, W. Richtering*, C. Aymonier, R. Thomann, L. Antonietti, S. Mecking*:
Solution Structure of Metal Particles Prepared in Unimolecular Reactors of Amphiphilic Hyperbranched Macromolecules.
Macromolecules 2004, 37, 7893 - 7900. DOI: 10.1021/ma048965g

V. M. Garamus, T. V. Maksimova, W. Richtering*, H. Kautz, H. Frey, U. Schlotterbeck, S. Mecking:
Hyperbranched Polymers: Structure of Hyperbranched Polyglycerol and Amphiphilic Poly(glycerol ester)s in Dilute Aqueous and Non-aqueous Solution.
Macromolecules 2004, 37, 8394 - 8399. DOI: 10.1021/ma0490909

L. Kolb, R. Thomann, S. Mecking*:
Multiphase Polymer Dispersions and Nanocomposites by Catalytic/Free Radical Emulsion Polymerization.
Macromol. Rapid Commun. 2004, 25, 1824 - 1828. DOI: 10.1002/marc.200400346

A. Bastero, L. Kolb, P. Wehrmann, F. M. Bauers, I. Göttker gen. Schnetmann, V. Monteil, R. Thomann, M. M. Chowdhry, S. Mecking*:
Catalytic Ethylene Polymerization in Aqueous Emulsion: Catalyst Tailoring and Synthesis of Very Small Latex Particles.
Polym. Mat. Sci. Eng. 2004, 90, 740 - 741. KOPS

2003

F. M. Bauers, R. Thomann, S. Mecking*:
Submicron Polyethylene Particles Obtained by Catalytic Emulsion Polymerization.
J. Am. Chem. Soc. 2003, 125, 8838 - 8840. DOI: 10.1021/ja034504j

F. M. Bauers, M. M. Chowdhry, S. Mecking*:
Catalytic Polymerization of Ethylene in Emulsion with a Simple In Situ Catalyst.
Macromolecules 2003, 36, 6711 - 6715. DOI: 10.1021/ma034164m

R. Sablong, U. Schlotterbeck, D. Vogt*, S. Mecking*:
Catalysis with Soluble Hybrids of Highly Branched Macromolecules with Palladium Nanoparticles in a Continuously Operated Membrane Reactor.
Adv. Synth. Catal. 2003, 345, 333 - 336. DOI: 10.1002/adsc.200390034

F. M. Bauers, M. A. Zuideveld, R. Thomann, S. Mecking*:
Catalytic Polymerization in Emulsion.
Macromol. Chem. Phys. 2003, 204, F7 - F8 (proceedings paper Makromolekulares Kolloquium 2003). KOPS

S. Mecking, J. Claverie:
Transition Metal Catalyzed Polymerization in Aqueous Systems.
Late Transition Metal Polymerization Catalysis (Eds.: L.S. Boffa, S. Kacker, B. Rieger, S. Striegler). Wiley-VCH, Weinheim, 2003, p. 231 - 278. KOPS

2002

W. Keim, S. Killat, C. F. Nobile, G. P. Suranna*, U. Englert, R. Wang, S. Mecking, D. L. Schröder:
Synthesis, Characterization and Catalytic Activity of Pd(II) and Ni(II) Complexes with New Cyclic α-Diphenylphosphino-Ketoimines.
J. Organomet. Chem. 2002, 662, 150 - 171. DOI: 10.1016/S0022-328X(02)01903-4

C. Aymonier, U. Schlotterbeck, L. Antonietti, P. Zacharias, R. Thomann, J.C. Tiller*, S. Mecking*:
Hybrids of Silver Nanoparticles with Amphiphilic Hyperbranched Macromolecules Exhibiting Antimicrobial Properties.
Chem. Commun. 2002, 3018 - 3019. DOI: 10.1039/B208575E

D. L. Schröder, W. Keim, M. A. Zuideveld, S. Mecking*:
Ethylene Polymerization by Novel, Easily Accessible Catalysts Based on Nickel(II)-Diazene Complexes.
Macromolecules 2002, 35, 6071 - 6073. DOI: 10.1021/ma012171+

A. Held, L. Kolb, M. A. Zuideveld, R. Thomann, S. Mecking*, M. Schmid*, R. Pietruschka, E. Lindner, M. Sunjuk, M. Khanfar:
Aqueous Polyketone Latices Prepared with Water-Insoluble Palladium(II) Catalysts.
Macromolecules 2002, 35, 3342 - 3347. DOI: 10.1021/ma0120411

S. Mecking*, A. Held, F. M. Bauers:
Aqueous Catalytic Polymerization of Olefins.
Angew. Chem Int. Ed. 2002, 41, 544 - 561. DOI: 10.1002/1521-3773(20020215)41:4%3C544::AID-ANIE544%3E3.0.CO;2-U
Angew. Chem. 2002, 114, 564 - 582. DOI: 10.1002/1521-3757(20020215)114:4%3C564::AID-ANGE564%3E3.0.CO;2-6

2001

E. Schwab, S. Mecking*:
Immobilization of a Catalytically Active Rhodium Complex by Electrostatic Interactions of Multiply Charged Phosphine Ligands with a Soluble Polyelectrolyte and Recovery by Ultrafiltration.
Organometallics 2001, 20, 5504 - 5506. DOI: 10.1021/om0107542

F. M. Bauers, S. Mecking*:
High-Molecular-Weight Polyethylene Aqueous Latices by Catalytic Polymerization.
Angew. Chem Int. Ed. 2001, 40, 3020 - 3022. DOI: 10.1002/1521-3773(20010817)40:16%3C3020::AID-ANIE3020%3E3.0.CO;2-7
Angew. Chem. 2001, 113, 3112 - 3115. DOI: 10.1002/1521-3757(20010817)113:16%3C3112::AID-ANGE3112%3E3.0.CO;2-Q

S. Meier, H. Reisinger, R. Haag, S. Mecking, R. Mülhaupt*, F. Stelzer:
Carbohydrate Analogue Polymers by Ring Opening Metathesis Polymerization (ROMP) and Subsequent Catalytic Dihydroxylation.
Chem. Commun. 2001, 855 - 856. DOI: 10.1039/B100680K

A. Held, F. Weiss, S. Mecking*:
Aqueous Ethylene Polymerization: Stability of Cationic Pd(II) Complexes and Polymer Properties.
Polym. Prepr. 2001, 42, 466 - 467. KOPS

S. Mecking*, U. Schlotterbeck, R. Thomann, M. Soddemann, M. Stieger, W. Richtering, H. Kautz:
Formation of Metal Nanoparticles in Modified Hyperbranched Polyglycerols and Use as Soluble Separable Catalysts.
Polym. Mat. Sci. Eng. 2001, 84, 511 - 512. KOPS

S. Mecking*, A. Held, F. M. Bauers:
Water as a Reaction Medium for Coordination Polymerization of Ethylene.
Advances on Organometallic Catalysts and Olefin Polymerization in China and Germany (Eds. J. Sun, C. Janiak). Chemical Industry Press, Beijing, 2001, p. 149 - 158.

F. M. Bauers, S. Mecking*:
Aqueous Homo- and Copolymerization of Ethylene by Neutral Nickel(II) Complexes.
Macromolecules 2001, 34, 1165 - 71. DOI: 10.1021/ma001704w

S. Mecking:
Olefin Polymerization by Late Transition Metal Complexes - A Root of Ziegler Catalysts Gains New Ground.
Angew. Chem Int. Ed. 2001, 40, 534 - 540. DOI: 10.1002/1521-3773(20010202)40:3%3C534::AID-ANIE534%3E3.0.CO;2-C
Angew. Chem. 2001, 113, 550 - 557. DOI: 10.1002/1521-3757(20010202)113:3%3C550::AID-ANGE550%3E3.0.CO;2-Z

2000

A. Held, S. Mecking*:
Coordination Polymerization in Water Affording Amorphous Polyethylenes.
Chem. – Eur. J. 2000, 6, 4623 - 4629. DOI: 10.1002/1521-3765(20001215)6:24%3C4623::AID-CHEM4623%3E3.0.CO;2-%23

S. Mecking*, R. Thomann:
Core-Shell Microspheres of a Catalytically Active Rhodium Complex bound to a Polyelectrolyte-coated Latex.
Adv. Mater. 2000, 12, 953 - 956. DOI: 10.1002/1521-4095(200006)12:13%3C953::AID-ADMA953%3E3.0.CO;2-J

S. Mecking*, R. Thomann, H. Frey, A. Sunder:
Preparation of Catalytically Active Palladium Nanoclusters in Compartments of Amphiphilic Hyperbranched Polyglycerols.
Macromolecules 2000, 33, 3958 - 3960. DOI: 10.1021/ma000301t

S. Mecking:
Cationic Nickel and Palladium Complexes with Bidentate Ligands for the C-C Linkage of Olefins.
Coord. Chem. Rev. 2000, 203, 325 - 351. DOI: 10.1016/S0010-8545(99)00229-5

S. Mecking*, F. M. Bauers:
Water as a Reaction Medium for Nickel(II)-catalyzed Ethylene Polymerization.
Polym. Prepr. 2000, 41, 209 - 210. KOPS

A. Held, F. M. Bauers, S. Mecking*:
Coordination Polymerization of Ethylene in Water by Palladium(II) and Nickel(II) Catalysts.
Chem. Commun. 2000, 301 - 302. DOI: 10.1039/A908633A

Up to 1999

S. Mecking:
Reactor Blending with Early/Late Transition Metal Catalyst Combinations in Ethylene Polymerization.
Macromol. Rapid Commun. 1999, 20, 139 - 143. DOI: 10.1002/(SICI)1521-3927(19990301)20:3%3C139::AID-MARC139%3E3.0.CO;2-R

S. Mecking, L. K. Johnson, L. Wang, M. Brookhart*:
Mechanistic Studies of the Palladium-Catalyzed Copolymerization of Ethylene and a-Olefins with Methyl Acrylate.
J. Am. Chem. Soc. 1998, 120, 888 - 899. DOI: 10.1021/ja964144i

S. J. McLain, E. F. McCord, S. D. Arthur, E. Hauptman, J. Feldman, W. A. Nugent, L. K. Johnson, S. Mecking, M. Brookhart*:
New Routes to Ester and Acid Functionalized Polyethylene.
Polym. Mat. Sci. Eng. 1997, 76, 246 -247. KOPS

M. Brookhart*, L. K. Johnson, C. M. Killian, S. Mecking, D. J. Tempel:
Palladium(II)- and Nickel(II)-Catalyzed Olefin Polymerization.
Polym. Prepr. 1996, 37, 254 - 255. KOPS

L. K. Johnson, S. Mecking, M. Brookhart*:
Copolymerization of Ethylene and Propylene with Functionalized Vinyl Monomers by Palladium(II) Catalysts.
J. Am. Chem. Soc. 1996, 118, 267 - 268. DOI: 10.1021/ja953247i

S. Mecking, W. Keim*:
Cationic Palladium η³-Allyl Complexes with Hemilabile P,O-Ligands: Synthesis and Reactivity. Insertion of Ethylene into the Pd-Allyl Function.
Organometallics 1996, 15, 2650 - 2656. DOI: 10.1021/om960061z

A. Macchioni, P. S. Pregosin, P. F. Engel, S. Mecking, M. Pfeffer*, J.-C. Daran, J. Vaissermann:
Multinuclear NMR Studies and Reaction with tert-Butyl Isocyanide of Dinuclear Tungsten - or Molybdenum - Palladium µ-Alkylidene Complexes. X-ray Structure of [PdI{µ-C(p-tolyl)dmba}{µ-CO}Mo(Cp)(CN-t-Bu)₂].
Organometallics 1995, 14, 1637 - 1645. DOI: 10.1021/om00004a018

W. Keim*, H. Maas, S. Mecking:
Palladium Catalyzed Alternating Cooligomerization of Ethylene and Carbon Monoxide to Unsaturated Ketones.
Z. Naturforsch. B 1995, 50b, 430 - 438. ZFN

G. J. P. Britovsek, W. Keim*, S. Mecking, D. Sainz, T. Wagner:
Hemilabile P,O-Ligands in Palladium Catalysed C-C Linkages: Codimerization of Ethylene and Styrene and Cooligomerization of Ethylene and Carbon Monoxide.
J. Chem. Soc. Chem. Commun. 1993, 1632 - 1634. DOI: 10.1039/C39930001632

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